Step 1 : Click over “Customize and control Google Chrome” icon which is the following icon 
  Step 2 :  Then Click Settings” from the Menu

Step 3 : Scroll the Settings window  until you reach “Show advanced Settings … “

Step 4 : Click Over “Show advanced Settings … “ link
Step 5 : A New Section will show up, Scroll until you reach “Downloads” Heading

Step 6 : Tick Ask where to save each file before downloading 
and that will keep Google Chrome asking for where to locate files each time you would like to download a document.